The Tripodal Ligand’s 4f Complexes: Use in Molecular Magnetism
نویسندگان
چکیده
A predictable type of coordination is a key property tripodal ligands. Homo- and heteroleptic lanthanide complexes with ligands are representative class compounds. However, despite the fact that many them paramagnetic, their magnetic behavior poorly studied. This because photophysical catalytic properties considered more attractive. In present review, we try to summarize available structural information only few examples data on in order draw some conclusions about prospect such design quantum molecular magnets involving (Ln) ions. We would also like catch reader’s attention that, consideration large part currently known Ln compounds ligands, this review not exhaustive. our goal magnetochemists theoreticians whole niche air-stable still out field vision.
منابع مشابه
Copper complexes of nitrogen-anchored tripodal N-heterocyclic carbene ligands.
Incorporation of a nitrogen functionality into a tripodal N-heterocyclic carbene ligand system affords the first N-anchored tetradentate tris-carbene ligands TIMEN(R) (R = Me (5a), t-Bu (5b), Bz (5c)). Treatment of the methyl derivatized [H(3)TIMEN(Me)](PF(6))(3) imidazolium salt (H(3)5a) with silver oxide yields the silver complex [(TIMEN(Me))(2)Ag(3)](PF(6))(3) (9), which, in a ligand transfe...
متن کاملSynthesis, Spectroscopy and Magnetism of Alkoxobridged Dinuclear Copper(II) Complexes with 2 Amino Picolines as the Ligands
The synthesis, spectroscopic and magnetic characterization of a series of new alkoxo-bridged binuclear copper (II) compounds are described. All complexes have the general formula [Cu (m-OR)(L)2]2(ClO4)2 · x H2O, in which m-OR = CH3O-, C2H5O- or C3H7O-<e...
متن کاملMolecular Magnetism of Lanthanides Complexes and Networks
Lanthanides ions allows for the design of remarkable magnetic compounds with unique magnetic properties. One of their assets is that they can give rise easily to multi-functional materials. Such multi-functionality is found in the collection of papers of this Special Issue with contributions that highlight the unprecedented magnetic properties of lanthanide-based molecules together with chirali...
متن کاملTuning "kappticity" of tripodal ligands.
The synthesis and structural characterization of a series of tripodal tris(phosphine) ligands, containing SiMe2 elbow groups, is described. The significant steric congestion in these ligands, due to the silylmethyl substituents, is manifest both in the solid-state structures and in the solution NMR spectra of the free ligands. Variable temperature 1H{31P} NMR studies of one of the ligands, CH3C...
متن کاملDirected secondary interactions in transition metal complexes of tripodal pyrrole imine and amide ligands.
Tripodal pyrrole imine and amide ligands provide platforms for combined primary and secondary coordination sphere interactions in square planar Pd and Cu, and octahedral Ti complexes.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganics (Basel)
سال: 2023
ISSN: ['2304-6740']
DOI: https://doi.org/10.3390/inorganics11070307